Cv=Cp-nR

the enthalpy does not depend on pressure

pV is proportional to absolute temperature

Molar entropy always increases with temprerature

Molar entropy does not depend on pressure

ΔU=ΔH+Δ(pV) but only for perfect gas

ΔT=0

ΔU=w but only for perfect gas

q+w=TΔS

ΔU=w

doesn’t depend on temperature

is defined at standard pressure

is equal to TΔcSo+ΔcGo

is the the heat effect of reaction of combustion of 1 mole of a compound in air at standard pressure

none from above

is equal to zero

is equal to (C_v razy delta T)/T

is equal to delta(pV)/T

is equal to -delta(pV)/T

The heat capacity shows a discontinuity

thermal expresion coefficient shows a discontinuity

Entropy changes in continous way

Entropy shows a discontinuity

The transition entropy is delta H=T delta trans S

at the triple point of a substance is equal for solid, liquid and vapor

always increases with temperature

has a minimum at the critical point

can be defined as (dG/dξ)T

doesn’t depend on pressure

is 0 for perfect gases

is equal to RTlnx in system (henry's law)

is equal to Rlnx in system (henry's law)

is equal to -RTlnx in system (raoult's law)

is equal to -Rlnx in system (raoult's law)

depends on the molar fractions of reactants and products in the mixture

has a temperature dependence given by the Van’t Hoff law

does not depend on temperature

does not depend on the total volume of the reaction mixture

depends on the partial pressures in the reaction mixture